• 文献标题:   Reduced Graphene Oxide Produced by a Green Reduction Method and Its Application in Cu2+ Adsorption for Catalyzing the Reduction of 4-Nitrophenol
  • 文献类型:   Article
  • 作  者:   HE YQ, MA JK, WU T, LIU Y, WANG XR, GONG QJ, WANG W, LIU Y, GAO JP
  • 作者关键词:   graphene, reduction, adsorption, catalysi
  • 出版物名称:   SCIENCE OF ADVANCED MATERIALS
  • ISSN:   1947-2935 EI 1947-2943
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   3
  • DOI:   10.1166/sam.2014.1959
  • 出版年:   2014

▎ 摘  要

A green approach for the preparation of a stable reduced graphene oxide (RGO) suspension from graphene oxide (GO) was developed. This method used arginine (Arg) as the reductant and carboxyl methyl cellulose (CMC) as the stabilizing agent. Analysis shows that Arg can efficiently reduce GO at a comparatively low temperature, and CMC adsorbed onto RGO allows a stable RGO aqueous dispersion to be formed. Since Arg and CMC are natural and environmental friendly chemicals, this approach provides a green method to produce stable RGO from GO on a large scale. CMC/RGO foams were fabricated and their adsorption behavior for methylene blue and heavy metal ions was investigated. After CMC/RGO foams were used to adsorb Cu ions, the foams were then treated with sodium borohydride to transform Cu ions into nanoparticles. These Cu nanoparticle-containing CMC/RGO foams showed superior catalytic performance for the reduction of 4-nitrophenol. So this method offers a way to turn a recovered waste material into something useful.