▎ 摘　　要

Mono layer graphene was prepared on an Ir(111) substrate where it exhibits a 25 X 25 A(2) moire pattern. Molecular hydrogen was dosed first, allowing it to dissociate on open areas of the Ir substrate. The generated H atoms formed an intercalated reservoir that can bind to the graphene subsequently. Next, atomic hydrogen was dosed, which binds to the graphene sheet and also initiates the transfer of H from the Ir substrate to the graphene sheet. The opposite sides of the sheet can be hydrogenated with isotope selectivity, as a sequence of difference isotopes, H or D, can be chosen at will in the preparation procedure. Sum-frequency generation spectra prove that as consequence of the dosing sequence, C-H bonds are predominantly pointing toward the Ir substrate side when H-2 is dosed first and alternatively toward the vacuum side when D-2 is dosed first.