• 文献标题:   Electrochemical determination of hydrogen peroxide on a gold nanoparticle-nitrogen-doped graphene glassy carbon electrode
  • 文献类型:   Article
  • 作  者:   LIU F, ZHANG JW, LIU YN, NIU SY, WAN J
  • 作者关键词:   differential pulse voltammetry, electrochemical sensor, hydrogen peroxide, nitrogendoped grapheme
  • 出版物名称:   INSTRUMENTATION SCIENCE TECHNOLOGY
  • ISSN:   1073-9149 EI 1525-6030
  • 通讯作者地址:   Qingdao Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.1080/10739149.2017.1410488
  • 出版年:   2018

▎ 摘  要

A novel nonenzymatic sensor based on gold nanoparticle-nitrogen-doped graphene was synthesized by electrochemical sequential deposition on the surface of a glassy carbon electrode. Nitrogen-doped graphene was synthesized by a hydrothermal method using graphene oxide and carbamide as the raw materials mixed in specific proportions. The gold nanoparticles were used in the electrochemical sensor to provide unique electronic and electrochemical properties. Under the optimized conditions, hydrogen peroxide was determined by differential pulse voltammetry with a linear relationship for concentrations from 1.0x10(-7) to 1.0x10(-5)molL(-1). The detection limit was 4.9x10(-8)molL(-1) (according to the 3 sigma rule) and the recoveries were 95.0-98.0%. This sensor is simple, reproducible, and demonstrates that nitrogen-doped graphene oxide has potential applications for electrochemical sensors.