• 文献标题:   A simplified chemical reduction method for preparation of graphene: Dispersity, reducibility and mechanism
  • 文献类型:   Article
  • 作  者:   WANG R, LIU Y, ZHANG YZ, WANG LL, YANG G, SHEN F, DENG SH, ZHANG XH, HE Y, LUO L
  • 作者关键词:   chemical reduction, graphene, defect, suspension
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Sichuan Agr Univ
  • 被引频次:   5
  • DOI:   10.1016/j.ceramint.2016.09.061
  • 出版年:   2016

▎ 摘  要

Graphene was prepared by a simple chemical reduction of graphite oxide in the dimethylacetamide (DMAc)/H2O mixture solvent. The results from Fourier transform infrared spectroscopy, Raman spectroscopy and X-ray photoelectron spectroscopy indicated that the reduction degree of graphene products increased with the increase in the volume ratio of DMAc and water (V-DmAc/V-H2o), and kept constant when the V-DmAc/V-H2O ratio was equal or greater than 1. A reduction mechanism from graphite oxide to graphene was proposed. The epoxy groups and hydroxyl on the graphite oxide (GO) surface could be eliminated in the reduction process, whereas the carbonyl was converted to a hydroquinone structure. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.