• 文献标题:   Graphene-Based Organic Electrochemical Capacitors for AC Line Filtering
  • 文献类型:   Article
  • 作  者:   CHI FY, LI C, ZHOU QQ, ZHANG M, CHEN J, YU XW, SHI GQ
  • 作者关键词:   ac linefiltering, electrochemical reduction, organic electrolyte, ultrafast electrochemical capacitor
  • 出版物名称:   ADVANCED ENERGY MATERIALS
  • ISSN:   1614-6832 EI 1614-6840
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   17
  • DOI:   10.1002/aenm.201700591
  • 出版年:   2017

▎ 摘  要

Less-defective graphene oxide sheets with a small average size of 0.7 mu m are electrochemically reduced to form a hydrogel film with highly oriented porous structure. It is applied as the electrode of organic electrochemical capacitor ( OEC) after solvent change with organic electrolyte and deep reduction in this organic medium. At 120 Hz, the typical OEC exhibits a high areal specific energy density of 472 mu F V-2 cm(-2) with a wide workable voltage window of 2.5 V, a phase angle of -80.5 degrees, a resistor-capacitor time constant (tau(RC)) of 0.219 ms, and an excellent electrochemical stability. Thus, it is promising to replace aluminum electrolytic capacitors for AC line filtering. Furthermore, two identical OECs connected in series keep the performance of single device, making them practically applicable in electronics.