• 文献标题:   Nanosheet-templated graphene oxide membranes for fast molecule separation
  • 文献类型:   Article
  • 作  者:   LIN Z, HU C, LIU QL, ZHANG QG
  • 作者关键词:   dspacing control, laminar membrane, molecule separation, nanosheettemplated membrane, sacrificed intercalator
  • 出版物名称:   AICHE JOURNAL
  • ISSN:   0001-1541 EI 1547-5905
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/aic.17818 EA JUL 2022
  • 出版年:   2022

▎ 摘  要

Intercalated laminar membrane with controllable interlayer spacing (d-spacing) is one of the most effective membranes for fast molecule separation. In this work, we demonstrate a versatile strategy to create nanosheet-templated water channels in laminar graphene oxide (GO) membranes. The 1.2 nm-thick nickel hydroxide nanosheets as sacrificed intercalators provide a chance to control the d-spacing. The resultant membranes have controllable channels and exhibit over six times higher water permeance than the unintercalated membrane. The 880 nm-thick nanosheet-templated GO (NST-GO) membrane has accurate d-spacing of about 1.14 nm and shows high water permeance of 120.3 L m(-2) h(-1) bar(-1) and good molecule separation property, reflecting in high rejection for larger dyes (90.1% for erythrosine B [EB]), while low rejection for smaller dyes (58.3% for methylene blue [MB]). Furthermore, this strategy of intercalating and sacrificing nanosheets has higher potential than traditional intercalation in controlling d-spacing of laminar membranes.