• 文献标题:   Turn-On Detection of Cs Ions Based on Conjugated Polymer-Graphene Oxide Composite
  • 文献类型:   Article
  • 作  者:   JANG G, CHO E, HARWOOD LM, LEE TS
  • 作者关键词:   conjugated polymer, graphene oxide, cs ion detection, fluorescence, sensor
  • 出版物名称:   POLYMERKOREA
  • ISSN:   0379-153X
  • 通讯作者地址:   Chungnam Natl Univ
  • 被引频次:   0
  • DOI:   10.7317/pk.2019.43.2.302
  • 出版年:   2019

▎ 摘  要

New type of "turn-on" fluorescent sensor for Cs ion was developed using a composite of blue-emissive conjugated polymer (CP) and graphene oxide (GO). Ethylene glycol units were introduced to the side chain of CP, which could interact with Cs ions. The CP and GO formed a stable, nonfluorescent composite, because of hydrophobic and pi-pi interactions between them. In the presence of Cs ions, the CP was released from the CP-GO composite because of higher affinity of Cs ions with ethylene glycol units in the CP. Such a weaker interaction between CP and GO led to the recovery of initial blue fluorescence of the CP. The degree of fluorescence restoration would be a measure of the concentration of Cs ions. Thus, fluorescence "turn-on" from CP-GO was attributed to the presence of Cs ions.