• 文献标题:   Enhancing corrosion protection properties of sol-gel coating by pH-responsive amino-silane functionalized graphene oxide-mesoporous silica nanosheets
  • 文献类型:   Article
  • 作  者:   XIONG LL, LIU JH, LI YQ, LI SM, YU M
  • 作者关键词:   aminosilane functionalization, compatibility, phresponsive release, active protection
  • 出版物名称:   PROGRESS IN ORGANIC COATINGS
  • ISSN:   0300-9440
  • 通讯作者地址:   Beihang Univ
  • 被引频次:   3
  • DOI:   10.1016/j.porgcoat.2019.06.007
  • 出版年:   2019

▎ 摘  要

Amino-silane functionalized graphene oxide-ordered mesoporous silica nanocontainer was synthesized to load corrosion inhibitor benzotriazole, and the synthesized two-dimensional composite was named as fGS-BTA. Its compatibility and dispersion stability in sol solution was prominently reinforced by amino-silane functionalization. Meanwhile, amino-silane as pH-driven "nanogate" suppressed the premature leakage of inhibitor, which endowed fGS-BTA nanocomposite the stimuli-responsive release under alkaline condition. Electrochemical impedance spectroscopy of intact and scratched sol-gel coating filled with fGS-BTA nanosheets showed the enhanced barrier property and the active protection capacity.