• 文献标题:   Pre-stabilized reduced graphene oxide by ammonia as carrier for Ni(OH)(2) with excellent electrochemical property
  • 文献类型:   Article
  • 作  者:   ZHANG JL, LIU HD, HUANG LH, TAN SZ, MAI WJ, CAI X
  • 作者关键词:   reduced graphene oxide, nickel hydroxide, ammonia, supercapacitor
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Jinan Univ
  • 被引频次:   10
  • DOI:   10.1007/s10008-014-2595-8
  • 出版年:   2015

▎ 摘  要

An advanced electrochemical pseudocapacitor material based on reduced graphene oxide and nickel hydroxide (rGO&Ni(OH)(2)) was prepared by an easy process where ammonia acted as a pre-stabilizer that could be easily removed. The results showed that the agglomeration and re-stacking of rGO could be effectively prevented, resulting in few-layer rGO nanosheet with high specific surface area of 891.22 m(2)/g which could supply large available area for loading nanoparticle. After the incorporation of Ni(OH)(2) nanoparticle, the rGO&Ni(OH)(2) composite owned excellent electrochemical performance thanks to effective prevention of agglomeration and re-stacking of rGO with large size of the sp(2) domain, no residual of pre-stabilizer of ammonia, and tight contact between rGO and Ni(OH)(2). Specifically, the rGO&Ni(OH)(2) electrode exhibited excellent stability at scan rates from 100 to 300 mV/s. A high specific capacitance of 1,008 F/g was obtained at high current density of 42 A/g in 6 mol/L KOH aqueous electrolyte, and the specific capacitance demonstrated good rate capability. Moreover, rGO&Ni(OH)(2) electrode showed a long cycle life, retaining 74 % specific capacitance after 2,000 cycles at current density of 6 A/g. The advantages of easy process and excellent electrochemical property suggested great potential application of rGO&Ni(OH)(2) in supercapacitors.