• 文献标题:   Production of Nitrogen-Doped Graphene by Low-Energy Nitrogen Implantation
  • 文献类型:   Article
  • 作  者:   ZHAO W, HOFERT O, GOTTERBARM K, ZHU JF, PAPP C, STEINRUCK HP
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Univ Erlangen Nurnberg
  • 被引频次:   74
  • DOI:   10.1021/jp209927m
  • 出版年:   2012

▎ 摘  要

Nitrogen doping of graphene is a suitable route to tune the electronic structure of graphene, leading to n-type conductive materials. Herein, we report a simple way to insert nitrogen atoms into graphene by low-energy nitrogen bombardment, forming nitrogen-doped graphene. The formation of nitrogen-doped graphene is investigated with high resolution X-ray photoelectron spectroscopy, allowing to determine the doping level and to identify two different carbon nitrogen species. By application of different ion implantation energies and times, we demonstrate that a doping level of up to 0.05 monolayers is achievable and that the branching ratio of the two nitrogen species can be varied.