• 文献标题:   Amorphous Si-island/graphene oxide-carbon hybrid anode thin film for a lithium-ion battery
  • 文献类型:   Article
  • 作  者:   LEE SY, KIM JH, HWANG WS, KIM S, BAE JS, KIM JP, JEONG ED
  • 作者关键词:   lithiumion battery, anode, silicon island, graphene oxide, multilayered structure
  • 出版物名称:   THIN SOLID FILMS
  • ISSN:   0040-6090
  • 通讯作者地址:   Korea Basic Sci Inst
  • 被引频次:   1
  • DOI:   10.1016/j.tsf.2017.11.038
  • 出版年:   2018

▎ 摘  要

A multi-layered graphene oxide-carbon/Si-island thin film/graphene oxide-carbon electrode is prepared as a very promising anode material for rechargeable Li-ion batteries. In this approach, graphene oxide-carbon layers are introduced to improve the adhesion (between the Si-island and copper current collector) and conductivity. The Si-island (diameter: 700 mu m; array distance: 480 mu m) is sputtered using a metal shadow mask. The strain during the insertion and extraction of the Li ions is adequately suppressed by the space among the neighboring Si-islands. This results in a superior cycle retention of 86.3% with a reversible discharge capacity of 940 mAh g(-1) after 105 cycles.