• 文献标题:   Reduced graphene oxide and Fe-2(MoO4)(3) composite for sodium-ion batteries cathode with improved performance
  • 文献类型:   Article
  • 作  者:   NIU YB, XU MW
  • 作者关键词:   fe2 moo4 3, graphene oxide, sodiumion batterie, hydrothermal
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Southwest Univ
  • 被引频次:   11
  • DOI:   10.1016/j.jallcom.2016.02.223
  • 出版年:   2016

▎ 摘  要

Fe-2(MoO4)(3)@reduced graphene oxide (FMO@rGO) composite have been synthesized by precipitation-hydrothermal method. Herein, the graphene oxide in the present synthesis acts not only as baffles between particle and particle that helps to prevent the increase of particle size, but also as conductive networks after hydrothermal treatment, providing high electronic conductivity between particle and particle. The special surface area of the as-prepared materials significantly increases from 19.738 m(2) g(-1) (FMO) to 51.401 m(2) g(-1) (FMO@rGO), which undoubtedly provide more interface area between the active materials and the electrolyte. As a cathode material for sodium-ion batteries, the FMO@rGO composite delivers high discharge capacity at 0.5 C, which is comparable to theoretical capacity and literatures, and impressive rate performance. As the current density is at 5 C, for the first time, the initial specific capacity of FMO@rGO composite is about 68.2 mAh g(-1), and it remains 56.5 mAh g(-1) after 100 cycles, of which the excellent electrochemical performance is mainly attributed to good conductivity, high specific surface area and significantly enhanced diffusion coefficient. (C) 2016 Elsevier B.V. All rights reserved.