• 文献标题:   A screen printed carbon electrode modified with a lamellar nanocomposite containing dendritic silver nanostructures, reduced graphene oxide, and -cyclodextrin for voltammetric sensing of nitrite
  • 文献类型:   Article
  • 作  者:   ZHE TT, SUN XY, WANG QZ, LIU YN, LI R, LI F, WANG L
  • 作者关键词:   electrodeposition, nitrite detection, linear sweep voltammetry, electrochemical sensor, composite material
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Northwest A F Univ
  • 被引频次:   5
  • DOI:   10.1007/s00604-019-3414-9
  • 出版年:   2019

▎ 摘  要

A disposable sensor is described for the determination of nitrite. A screen printed carbon electrode (SPCE) was modified with a 3D lamellar nanocomposite prepared by one-step electrodeposition from dendritic silver nanostructures, reduced graphene oxide, and -cyclodextrin. The modified SPCE exhibits high electrocatalytic activity toward nitrite oxidation, typically at a working potential at around 0.76V (vs. Ag/AgCl). Sensitive and selective voltammetric detection of nitrite is demonstrated. The linear range extends from 1 to 2000M, the detection limit is 0.24M, and the sensitivity is 585.7AmM-1cm-2. The method was applied to the determination of nitrite in (spiked) pickles. Schematic presentation of fabrication of a screen printed carbon electrode modified with a lamellar nanocomposite containing dendritic silver nanostructures, reduced graphene oxide, and -cyclodextrin. Graphical abstract contains poor quality of text inside the artwork. Please do not re-use the file that we have rejected or attempt to increase its resolution and re-save. It is originally poor, therefore, increasing the resolution will not solve the quality problem. We suggest that you provide us the original format. We prefer replacement figures containing vector/editable objects rather than embedded images. Preferred file formats are eps, ai, tiff and pdf.We have provided the original format of graphical abstract in the attachment.