• 文献标题:   Deep Ultraviolet Photoluminescence of Water-Soluble Self-Passivated Graphene Quantum Dots
  • 文献类型:   Article
  • 作  者:   TANG LB, JI RB, CAO XK, LIN JY, JIANG HX, LI XM, TENG KS, LUK CM, ZENG SJ, HAO JH, LAU SP
  • 作者关键词:   graphene, quantum dot, deep ultraviolet, fluorescence, selfpassivated, graphene quantum dot
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851
  • 通讯作者地址:   Hong Kong Polytech Univ
  • 被引频次:   955
  • DOI:   10.1021/nn300760g
  • 出版年:   2012

▎ 摘  要

Glucose-derived water-soluble crystalline graphene quantum dots (GQDs) with an average diameter as small as 1.65 nm (similar to 5 layers) were prepared by a facile microwave-assisted hydrothermal method. The GQDs exhibits deep ultraviolet (DUV) emission of 4.1 eV, which is the shortest emission wavelength among all the solution-based QDs. The GQDs exhibit typical excitation wavelength-dependent properties as expected in carbon-based quantum dots. However, the emission wavelength is independent of the size of the GQDs. The unique optical properties of the GQDs are attributed to the self-passivated layer on the surface of the GQDs as revealed by electron energy loss spectroscopy. The photoluminescence quantum yields of the GQDs were determined to be 7-11%. The GQDs are capable of converting blue light into white light when the GQDs are coated onto a blue light emitting diode.