• 文献标题:   Fabrication of cuprous oxide nanoparticles-graphene nanocomposite for determination of acetaminophen
  • 文献类型:   Article
  • 作  者:   YANG H, LIU BD, DING YP, LI L, OUYANG XQ
  • 作者关键词:   cuprous oxide, graphene, acetaminophen, square wave voltammetry
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Shanghai Univ
  • 被引频次:   15
  • DOI:   10.1016/j.jelechem.2015.09.014
  • 出版年:   2015

▎ 摘  要

A glassy carbon electrode modified with cuprous oxide nanopartides-graphene composite film (Cu2O/GR) was prepared and applied to detect acetaminophen (AC). Scanning electron microscopy, energy dispersive X-ray spectroscopy and electrochemical impedance spectroscopy were applied for characterization of the proposed electrode. Cyclic voltammetry and square wave voltammetry were used to investigate the electrocatalysis oxidation of AC on Cu2O/GR. The linearity ranged from 2.0 x 10(-8) to 13 x 10(-8) M with a detection limit of 6.67 x 10(-9) M (S/N = 3) and the calculated sensitivity of 14,397.7 mu A mM(-1) cm(-2). Under optimal conditions, the sensor displays good stability and satisfactory results in real samples analysis. (C) 2015 Elsevier B.V. All rights reserved.