• 文献标题:   From Secondary to Primary Role in Alkaline Fuel Cells: Co-Decorated Graphene as Effective Catalyst for Ethanol Oxidation
  • 文献类型:   Article
  • 作  者:   BARAKAT NAM, MOTLAK M, NASSAR MM, ABDELKAREEM MA, MAHMOUD MS, ELNEWEHY MH, MOUSTAFA HM
  • 作者关键词:  
  • 出版物名称:   ECS ELECTROCHEMISTRY LETTERS
  • ISSN:   2162-8726 EI 2162-8734
  • 通讯作者地址:   Chonbuk Natl Univ
  • 被引频次:   8
  • DOI:   10.1149/2.0011401eel
  • 出版年:   2015

▎ 摘  要

This study proves that supporting of cobalt nanoparticles on graphene can modify its role to be the main electrocatalyst in ethanol oxidation process. The introduced cobalt-based catalyst was synthesized by reflux treatment of graphene oxide in presence of cobalt acetate at 150 degrees C followed by calcination of the obtained product in Ar atmosphere at 850 degrees C. Electrocatalytic activity investigation indicated that the introduced Co-decorated graphene can be effectively utilized in ethanol electrooxiation as the corresponding current density was 210 mA/cm(2) (at 3 M ethanol in 1 M KOH and 50 mV/s) and onset potential of 0.33 V [vs. Ag/AgCl]. (C) 2014 The Electrochemical Society. All rights reserved.