• 文献标题:   Reduced graphene oxide and polypyrrole/reduced graphene oxide composite coated stretchable fabric electrodes for supercapacitor application
  • 文献类型:   Article
  • 作  者:   ZHAO C, SHU KW, WANG CY, GAMBHIR S, WALLACE GG
  • 作者关键词:   stretchable electrode, graphene, polypyrrole, wearable, supercapacitor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Univ Wollongong
  • 被引频次:   53
  • DOI:   10.1016/j.electacta.2015.05.019
  • 出版年:   2015

▎ 摘  要

The advent of self-powered functional garments has given rise to a demand for stretchable energy storage devices that are amendable to integration into textile structures. The electromaterials (anode, cathode and separator) are expected to sustain a deformation of 3% to 55% associated with body movement. Here, we report a stretchable fabric supercapacitor electrode using commonly available nylon lycra fabric as the substrate and graphene oxide (GO) as a dyestuff. It was prepared via a facile dyeing approach followed by a mild chemical reduction. This reduced graphene oxide (rGO) coated fabric electrode retains conductivity at an applied strain of up to 200%. It delivers a specific capacitance of 12.3 F g(-1) at a scan rate of 5 mV s(-1) in 1.0 M lithium sulfate aqueous solution. The capacitance is significantly increased to 114 F g(-1) with the addition of a chemically synthesized polypyrrole (PPy) coating. This PPy-rGO-fabric electrode demonstrates an improved cycling stability and a higher capacitance at 50% strain when compared to the performance observed with no strain. (C) 2015 Elsevier Ltd. All rights reserved.