• 文献标题:   Electrodeposited Nickel Coating Reinforced with Chlorophyll-Reduced Graphene Oxide
  • 文献类型:   Article, Early Access
  • 作  者:   DAS S, BANTHIA S, MANNA JS, PALAI D, SENGUPTA S
  • 作者关键词:   auger spectroscopy, chlorophyll, corrosion, electrodeposition, nickel, reduced graphene oxide
  • 出版物名称:   ADVANCED ENGINEERING MATERIALS
  • ISSN:   1438-1656 EI 1527-2648
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/adem.202100254 EA AUG 2021
  • 出版年:   2021

▎ 摘  要

Nickel composite coating reinforced with reduced graphene oxide is fabricated by pulse electrodeposition method from a surfactant-free bath at different current densities. The reduction of graphene oxide is done by an ecofriendly method which uses chlorophyll (CHL) as the reducing agent. The CHL also acts as a stabilizer because of its amphiphilicity. Auger electron spectroscopy is used to study the surface morphology and characteristics of the deposited coatings. Nanoindentation is used to study the mechanical properties. Electrochemical techniques such as potentiodynamic polarization and electrochemical impedance spectroscopy are used to study the corrosion behavior in 3.5 wt% NaCl solution. The coatings are found to exhibit superior hardness, Young's modulus, and corrosion resistance when compared with the pure Ni coating. Hardness and corrosion resistance are found to improve almost tenfold at optimized condition. Scanning electron microscopy of the corroded surface of the coatings provides an insight into the corrosion process.