• 文献标题:   Folding/aggregation of graphene oxide and its application in Cu2+ removal
  • 文献类型:   Article
  • 作  者:   YANG ST, CHANG YL, WANG HF, LIU GB, CHEN S, WANG YW, LIU YF, CAO AN
  • 作者关键词:   graphene oxide, copper ion, aggregation, absorption, decontamination
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Shanghai Univ
  • 被引频次:   372
  • DOI:   10.1016/j.jcis.2010.07.042
  • 出版年:   2010

▎ 摘  要

Graphene oxide (GO) can be aggregated by Cu2+ in aqueous solution with a huge Cu2+ absorption capacity. The Cu2+ causes GO sheets to be folded and also to form large aggregates that were characterized by confocal microscopy and atomic force microscopy. The folding/aggregation is most likely triggered by the coordination between GO and Cu2+. The equilibrium Cu2+ concentrations and equilibrium absorption capacity of GO were measured to estimate the maximum absorption capacity of GO for Cu2+ and the absorption model. GO has a huge absorption capacity for Cu2+, which is around 10 times of that of active carbon. Representative results are presented and the implication to Cu2+ removal is discussed. (C) 2010 Elsevier Inc. All rights reserved.