• 文献标题:   Core-shell Mn3O4 nanorods with porous Fe2O3 layer supported on graphene conductive nanosheets for high-performance lithium storage application
  • 文献类型:   Article
  • 作  者:   WANG MY, HUANG Y, ZHU YD, YU M, QIN XL, ZHANG HM
  • 作者关键词:   transition metal oxide, graphene, coreshell structure, lithium storage
  • 出版物名称:   COMPOSITES PART BENGINEERING
  • ISSN:   1359-8368 EI 1879-1069
  • 通讯作者地址:   Northwestern Polytech Univ
  • 被引频次:   18
  • DOI:   10.1016/j.compositesb.2019.03.037
  • 出版年:   2019

▎ 摘  要

In this study, a core-shell nanostructure Fe2O3 coated grass-like Mn3O4 supported on graphene has been designed and fabricated via a facile and convenient hydrothermal method and thermal treatment routes. The Fe2O3 coated Mn3O4 nanorods with diameter of 35-40 nm are convolved by flexible graphene, which form a three-dimensional conductive network. As an anode for lithium-ion batteries, the as-prepared composite delivers an initial discharge/charge capacity of 1939.2/1393.5 mAh g(-1) with a promising coulombic efficiency of 71.9% and a reversible specific capacity of 795.4 mA g(-1) after 400 cycles at a high current density, which exhibits an upward trend in the capacity after long-term cycling as well. Both of the cross-linked structure and the synergistic effect are contributed to the enhance lithium-storage performance and dynamic characteristic, which reveals that the electrode holds a great potential as an anode material for rechargeable Li-ion batteries.