▎ 摘　　要

The commercialized aluminum electrolytic capacitors (AECs) currently used for alternating current (AC) line-filtering have low specific capacitances, making them usually the largest components in electronic circuits. Herein, an ultrathin free-standing graphene nanomesh film (GMF) with uniform and dense nanoholes has been successfully fabricated by an in-situ carbothermal reduction strategy on the basis of spontaneously assembled graphene hybrid film. Due to the carbothermal reduction reaction between carbon atoms of graphene and the metal oxide nanoparticles in-situ generated during assembly process, in-plane nanopores are generated within graphene film. The pore size and density of GMF can be conveniently tuned by annealing temperature. With large ion-accessible surface area, efficient ion diffusion and electron transport pathways, the typical GMF-based electrochemical capacitor (EC) exhibits a high volumetric capacitance of up to 7.6 F cm(-3) at 120 Hz, unprecedented power density of up to 3000 W cm(-3), ultrafast frequency response with a phase angle of -82.3 degrees, and a short resistor-capacitor time constant of 0.32 ms at 120 Hz, as well as long-term cycling stability. The performances of these ECs are superior to those of the state-of-the-art carbon-based ECs for this purpose; thus, it is promising to replace commercialized AECs for AC line-filtering in future electronics.