• 文献标题:   In situ fabrication of platinum/graphene composite shell on polymer microspheres through reactive self-assembly and in situ reduction
  • 文献类型:   Article
  • 作  者:   OH JS, LUONG ND, HWANG TS, HONG JP, LEE YK, NAM JD
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461
  • 通讯作者地址:   Sungkyunkwan Univ
  • 被引频次:   9
  • DOI:   10.1007/s10853-012-6848-6
  • 出版年:   2013

▎ 摘  要

We present a simple method to fabricate a uniform-sized graphene-metal-polymer composite microsphere of core-shell structure. On the surface of amine-functionalized polymer microsphere, graphene oxide (GO) sheets were affixed to give a core-shell structure by self-assembly process followed by the immobilization of platinum (Pt) ions to the assembled GO shell. Subsequently, they were chemically reduced in situ converting both GO and Pt ions to reduced GO (RGO) and Pt nanoparticles (NPs), respectively. As a result, a robust RGO-Pt composite shell, composed of RGO sheets and well-distributed Pt NPs, was fabricated on the microsphere surface. Meanwhile, the insulative GO shell was converted to the conductive RGO-Pt shell giving 24.0 S m(-1) of electrical conductivity. We demonstrated that the electrical property of the shell was significantly improved by the incorporation of Pt NPs.