▎ 摘 要
The interfacial mechanics and reinforcement by the graphene sheets in polymer matrix nanocomposites are important to their understanding. However, the methods available for their investigation remain a challenge. Here we report on a novel study in which the mechanical responses of a nano-sandwich model structure made of a single graphene sheet sandwiched between ultrathin polymer layers are determined using a nano-bubble inflation method. The stress-strain behavior of the graphene nano-sandwich shows that significant reinforcement is obtained at small strains and that the method also provides a measurement of the interfacial shear strength. In addition, the study provides data related to internal stresses that develop between the graphene layer and the polymer sandwich faces. (C) 2014 Elsevier Ltd. All rights reserved.