• 文献标题:   Ultrasonic-electrodeposition of Flower-like Graphene Nanosheets in Ionic Liquid and Its Sensing for Ascorbic Acid
  • 文献类型:   Article
  • 作  者:   SHENG QL, HE YP, ZHANG DW, ZHENG JB
  • 作者关键词:   electrodeposition, ultrasonic wave, ionic liquid, graphene nanosheet, ascorbic acid
  • 出版物名称:   JOURNAL OF THE CHINESE CHEMICAL SOCIETY
  • ISSN:   0009-4536
  • 通讯作者地址:   NW Univ Xian
  • 被引频次:   1
  • DOI:   10.1002/jccs.201200270
  • 出版年:   2013

▎ 摘  要

Choline chloride based ionic liquid Ethaline were employed as the supporting electrolyte, graphene (GE) nanosheet was prepared with ultrasonic wave assisted electrodeposition for the first time. Scanning electron microscope results indicated that flower-like GE nanosheets were obtained at the electrode surface. Energy dispersive X ray spectroscopy, Fourier transform infrared spectra and Raman spectra were used to characterize the composition of the flower-like GE nanosheets. Electrochemical methods showed that the flower-like GE nanosheets based sensor exhibited high electrocatalytic activity for ascorbic acid (AA) oxidation and can be potentially used for the sensitive amperometric sensing of AA. Amperometric experiments showed that the sensor displayed broad linearity from 0.25 mu M to 2.0 mM with a relative low detection limit-of 0.1 mu M (S/N = 3).