• 文献标题:   A resin-based methodology to synthesize N-doped graphene-like metal-free catalyst for oxygen reduction
  • 文献类型:   Article
  • 作  者:   KANG S, SHEN PK
  • 作者关键词:   ndoped graphemelike catalyst, ion exchange resin, metalfree catalyst, oxygen reduction reaction, electrochemistry
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Sun Yat Sen Univ
  • 被引频次:   13
  • DOI:   10.1016/j.electacta.2014.07.100
  • 出版年:   2014

▎ 摘  要

An ion-exchange resin-based methodology has been used to synthesize the N-doped graphene-like metal-free catalyst (NGMFC). This catalyst is hierarchical porous structured with high surface area. In acidic media, the NGMFC shows a high electrocatalytic performance and good stability towards oxygen reduction reaction (ORR) in rotating ring-disk electrode measurements. The onset potential of the catalyst for ORR is 0.99 V which is very close the onset potential of Pt/C catalyst. This research demonstrates that the ion-exchange resin-based methodology can be a potential alternative to produce efficient metal-free catalyst at extremely low cost for ORR. (C) 2014 Elsevier Ltd. All rights reserved.