• 文献标题:   Surface-enhanced Raman scattering of graphene caused by self-induced nanogating by GaN nanowire array
  • 文献类型:   Article
  • 作  者:   KIERDASZUK J, KAZMIERCZAK P, BOZEK R, GRZONKA J, KRAJEWSKA A, ZYTKIEWICZ ZR, SOBANSKA M, KLOSEK K, WOLOS A, KAMINSKA M, WYSMOLEK A, DRABINSKA A
  • 作者关键词:   graphene, gallium nitride, raman spectroscopy, surface enhanced raman scattering, kelvin probe force microscopy
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Univ Warsaw
  • 被引频次:   1
  • DOI:   10.1016/j.carbon.2017.11.061
  • 出版年:   2018

▎ 摘  要

A constant height of gallium nitride (GaN) nanowires with graphene deposited on them is shown to have a strong enhancement of Raman scattering, whilst variable height nanowires fail to give such an enhancement. Scanning electron microscopy reveals a smooth graphene surface which is present when the GaN nanowires are uniform, whereas graphene on nanowires with substantial height differences is observed to be pierced and stretched by the uppermost nanowires. The energy shifts of the characteristic Raman bands confirms that these differences in the nanowire height has a significant impact on the local graphene strain and the carrier concentration. The images obtained by Kelvin probe force microscopy show clearly that the carrier concentration in graphene is modulated by the nanowire substrate and dependent on the nanowire density. Therefore, the observed surface enhanced Raman scattering for graphene deposited on GaN nanowires of comparable height is triggered by self-induced nano-gating to the graphene. However, no clear correlation of the enhancement with the strain or the carrier concentration of graphene was discovered. (C) 2017 Elsevier Ltd. All rights reserved.