• 文献标题:   High rate integrated quasi-solid state supercapacitors based on nitrogen-enriched active carbon fiber/reduced graphene oxide nanocomposite
  • 文献类型:   Article
  • 作  者:   QIU XM, XIAO ZC, WANG LN, FAN LZ
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Univ Sci Technol Beijing
  • 被引频次:   10
  • DOI:   10.1016/j.carbon.2018.01.033
  • 出版年:   2018

▎ 摘  要

A nitrogen-enriched active carbon fiber/reduced graphene oxide nanocomposite was synthesized by electrospinning, calcination, self-assembled reduction, and post treatment nitrogen doping. The nitrogen content and C/O ratio of nitrogen-enriched active carbon fiber/reduced graphene oxide nanocomposite was up to 12 at.% and 28 after post process N-doping, respectively. High specific capacitance of 208 F g(-1) at 20 A g(-1) and excellent rate performance was shown in 6 mol L-1 KOH. Meanwhile, a specific capacitance of 212 F g(-1) was obtained at 3 A g(-1) and along with 99% capacitance retention after 10 000 cycles for quasi solid state supercapacitors. The excellent electrochemical performance is attributed to unique line-plane structure between the one dimensional active carbon fiber and the two dimensional reduced graphene oxide, and incorporation of nitrogen functional groups. (c) 2018 Elsevier Ltd. All rights reserved.