• 文献标题:   Reduced graphene oxide conjugate thymine as a new probe for ultrasensitive and selective fluorometric determination of mercury(II) ions
  • 文献类型:   Article
  • 作  者:   ABDELHAMID HN, WU HF
  • 作者关键词:   fluorescence, mercury, reduced graphene oxide, chemosensing, coordination chemistry
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Natl Sun Yat Sen Univ
  • 被引频次:   23
  • DOI:   10.1007/s00604-015-1461-4
  • 出版年:   2015

▎ 摘  要

We report on a highly sensitive and remarkably selective fluorometric assay for mercury(II) ion. It is based on the formation of a complex between thymine (T) and Hg(II) to form the [Hg(T)(2)(H2O)(2)](n) complex on the surface of reduced graphene oxide (rGO). This causes the fluorescence emission of rGO (peaking at 550 nm) to be quenched. Under optimal conditions, quenching is selective and fluorescence intensity is linearly related to the concentration of Hg(II) in the range between 100 and 700 nM. The limit of detection is 5 nM. In addition to its sensitivity and selectivity, the method is simple and direct.