• 文献标题:   Novel poly(3,4-ethylenedioxythiophene)/reduced graphene oxide incorporated with manganese oxide/iron oxide for supercapacitor device
  • 文献类型:   Article
  • 作  者:   AZMAN NHN, SULAIMAN Y, NAZIR MSMM, LIM HN
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCEMATERIALS IN ELECTRONICS
  • ISSN:   0957-4522 EI 1573-482X
  • 通讯作者地址:   Univ Putra Malaysia
  • 被引频次:   3
  • DOI:   10.1007/s10854-018-0415-0
  • 出版年:   2019

▎ 摘  要

A new composite namely PEDOT/RGO/MnO2/Fe2O3 was successfully developed from mixed metal oxides (MnO2 and Fe2O3) incorporated with poly(3,4-ethylenedioxythiophene) (PEDOT) and reduced graphene oxide (RGO). The surface morphology of the prepared composite revealed that MnO2 and Fe2O3 particles were successfully coated on the wrinkles and curly like-sheets of PEDOT/RGO in order to prevent aggregation of RGO layers and the composite was able to retain 80% of its initial specific capacitance in 1M KCl. The PEDOT/RGO/MnO2/Fe2O3 composite with Mn:Fe molar ratio of 2:3 displayed the highest specific capacitance of 287F/g indicating that Mn:Fe molar ratio gives significant effect on the supercapacitive performance of the composite. The specific capacitance of PEDOT/RGO/MnO2/Fe2O3 was higher than the composites with monometallic oxide i.e. PEDOT/RGO/MnO2 and PEDOT/RGO/Fe2O3. The PEDOT/RGO/MnO2/Fe2O3 composite also revealed the lowest charge transfer resistance that leads to the superior supercapacitive performance. The specific energy and specific power of PEDOT/RGO/MnO2/Fe2O3 composite were 11 Wh/kg and 1900W/kg at 4A/g, respectively. The results showed that the PEDOT/RGO/MnO2/Fe2O3 composite is a promising electrode material for high-performance supercapacitor.