• 文献标题:   Graphene oxide intercalation into self-assembled porphyrin J-aggregates
  • 文献类型:   Article
  • 作  者:   MARAKA HVR, ALSHAMMARI RM, ALATTAR N, LOPEZ SG, KEYES TE, RICE JH
  • 作者关键词:   graphene oxide, jaggragate, fluorescence
  • 出版物名称:   MATERIALS RESEARCH EXPRESS
  • ISSN:   2053-1591
  • 通讯作者地址:   Univ Coll Dublin
  • 被引频次:   2
  • DOI:   10.1088/2053-1591/1/4/045038
  • 出版年:   2014

▎ 摘  要

Studies are undertaken to examine graphene oxide intercalation into self-assembled J-aggregate porphyrin structures. Fluorescence lifetime and fluorescence anisotropy imaging were applied along with scanning electron microscopy to study the structure and optical properties of a graphene oxide/TMPyP hybrid composite material. It was seen that the presence of graphene oxide alters the macroscale and nanoscale self-assembled structures of TMPyP in addition graphene oxide also alters the optical activity reducing the emission intensity and exciton recombination lifetime. Evidence exists to support a model where planer-symmetric graphene oxide and TMPyP co-operate in the formation of self-assembled macro and nanostructures forming a composite with strong graphene oxide/TMPyP interaction.