• 文献标题:   Prussian Blue Nanocubes-SnO2 Quantum Dots-Reduced Graphene Oxide Ternary Nanocomposite: An Efficient Non-noble-metal Electrocatalyst for Non-enzymatic Detection of H2O2
  • 文献类型:   Article
  • 作  者:   CHAUHAN S, SAHOO S, SATPATI AK, SHARMA C, SAHOO PK
  • 作者关键词:   graphene, prussian blue nanocube, sno2 quantum dot, nonnoblemetal electrocatalyst, nonenzymatic sensor, hydrogen peroxide
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Indian Inst Technol Roorkee
  • 被引频次:   2
  • DOI:   10.1002/elan.202000041 EA APR 2020
  • 出版年:   2020

▎ 摘  要

Developing non-noble-metal electrocatalyst for non-enzymatic H2O2 sensing is highly attractive. A facile, two-step approach has been utilized for the synthesis of PBNCs/SnO2 QDs/RGO ternary nanocomposite. TEM, SEM, XPS, and XRD techniques were used to the characterize the structural and morphological properties of synthesized ternary nanocomposite. The synthesized ternary nanocomposite has been examined as an electrode material for the electrochemical detection of H2O2 using the Amperometry technique. Under optimum conditions, PBNCs/SnO2 QDs/RGO ternary nanocomposite performed very well in the electrocatalytic reduction of H2O2 with a linear dynamic range from 25-225 mu M (R-2=0.996) with a low detection limit of 71 nM (S/N=3). Compared to the recent literature, PBNCs/SnO(2)QDs/RGO ternary nanocomposite based modified electrode exhibit a wider linear dynamic range with a low detection limit. Furthermore, PBNCs/SnO2 QDs/RGO ternary nanocomposite based modified electrode showed an excellent anti-interference ability against various common interfering agents. The practical applicability of this ternary nanocomposite based modified electrode was further extended to determine the H2O2 in tap water with acceptable recovery. The present performance of PBNCs/SnO2 QDs/RGO ternary nanocomposite material towards H2O2 sensing might widen its application for developing a new type of non-noble metal-based non-enzymatic electrochemical biosensors.