• 文献标题:   Porous three-dimensional reduced graphene oxide merged with WO3 for efficient removal of radioactive strontium
  • 文献类型:   Article
  • 作  者:   MU WJ, YU QH, HU R, LI XL, WEI HY, JIAN Y
  • 作者关键词:   rgo/wo3, absorbent, radioactive ion, radioactive wastewater, sr
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   China Acad Engn Phys
  • 被引频次:   6
  • DOI:   10.1016/j.apsusc.2017.06.206
  • 出版年:   2017

▎ 摘  要

A simple hydrothermal method was used to prepare 3D nanostructured composite adsorbents of reduced graphene oxide (RGO) and WO3 (RGO/WO3). The analysis results suggest that it possesses a mesoporous 3D structure, in which WO3 nanorods are uniformly loaded on the surface of the RGO. Combining the benefits of GO and WO3, the composites exhibit a higher adsorption capacity for removing Sr2+ from aqueous solutions over a wide pH range (4-11). Adsorption isotherms show that the data fit the Langmuir isotherms well (R > 0.99), and the maximum adsorption capacity of 149.56 mg g(-1) was achieved, much higher than that for GO, WO3 and other similar adsorbents. Sr2+ adsorption on RGO/WO3 reached equilibrium within 200 min. The fast adsorption and high adsorption rate of RGO/WO3 are mostly attributable to the plentiful adsorption sites provided by the dispersed WO3 nanoparticles on the RGO surface. Furthermore, the existence of Na+ ions has no obvious effect on the removal of Sr2+ ions by RGO/WO3, and RGO/WO3 adsorbent can be repeated at least 5 times without significant loss of adsorption capacity by adsorption-desorption experiment. Thus, RGO/WO3 shows the potential ability for removal of Sr-90 from radioactive wastewater. (C) 2017 Elsevier B.V. All rights reserved.