• 文献标题:   Experimental study of the effects of graphene oxide on microstructure and properties of cement paste composite
  • 文献类型:   Article
  • 作  者:   YANG HB, MONASTERIO M, CUI HZ, HAN NX
  • 作者关键词:   graphene oxide go, cement based composite, hydration microstructure, calciumsilicatehydrate csh
  • 出版物名称:   COMPOSITES PART AAPPLIED SCIENCE MANUFACTURING
  • ISSN:   1359-835X EI 1878-5840
  • 通讯作者地址:   Shenzhen Univ
  • 被引频次:   29
  • DOI:   10.1016/j.compositesa.2017.07.022
  • 出版年:   2017

▎ 摘  要

Graphene oxide (GO) has been utilized to strengthen composite materials. In this study, the effects of GO on hydration degrees, macro-mechanical strength and calcium-silicate-hydrate (C-S-H) structure of cement based composites were investigated through comprehensive experimental tests. In addition, the aggregation mechanism of GO was verified by alkaline solution simulations, using Ca(OH)(2) and NH3 center dot H2O. Based on the experimental results, it was found that the 3-day and 7-day compressive strengths of cement based composites with 0.2 wt% of GO were increased by 35.7% and 42.3%, respectively as compared to the control. Moreover, the C-S-H structure of cement paste with GO was not observed to have undergone any change via qualitative and quantitative analyses combined with FT-IR, XRD and Si-29-NMR. Besides, the test results of TGA, DTG and Si-29-NMR showed that the hydrated degree of cement paste increased to 10.4% at 28 days when incorporating with 0.1% of GO. (C) 2017 Elsevier Ltd. All rights reserved.