• 文献标题:   SnS2 nanoplates embedded in 3D interconnected graphene network as anode material with superior lithium storage performance
  • 文献类型:   Article
  • 作  者:   TANG HL, QI X, HAN WJ, REN L, LIU YD, WANG XY, ZHONG JX
  • 作者关键词:   sns2, graphene, anode, lithium storage
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Xiangtan Univ
  • 被引频次:   30
  • DOI:   10.1016/j.apsusc.2015.07.091
  • 出版年:   2015

▎ 摘  要

Three-dimensional (3D) interconnected graphene network embedded with uniformly distributed tin disulfide (SnS2) nanoplates was prepared by a facile two-step method. The microstructures and morphologies of the SnS2/graphene nanocomposite (SSG) are experimentally confirmed by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Using the as-prepared SSG as an anode material for lithium batteries, its electrochemical performances were investigated by cyclic voltammograms (CV), charge/discharge tests, galvanostatic cycling performance and AC impedance spectroscopy. The results demonstrate that the as-prepared SSG exhibits excellent cycling performance with a capacity of 1060 mAh g(-1) retained after 200 charge/discharge cycles at a current density of 100 mA g(-1), also a superior rate capability of 670 mAh g(-1) even at such a high current density of 2000 mA g(-1). This favorable performance can be attributed to the unique 3D interconnected architecture with great electro-conductivity and its intimate contact with SnS2. Our results indicate a potential application of this novel 3D SnS2/graphene nanocomposite in lithium-ion battery. (C) 2015 Elsevier B.V. All rights reserved.