• 文献标题:   Improved corrosion protection of waterborne epoxy/graphene coating by combining non-covalent and covalent bonds
  • 文献类型:   Article
  • 作  者:   HE Y, CHEN CL, XIAO GQ, ZHONG F, WU YQ, HE Z
  • 作者关键词:   graphene, tannic acid, kh560, covalentnoncovalent bond, corrosion resistance
  • 出版物名称:   REACTIVE FUNCTIONAL POLYMERS
  • ISSN:   1381-5148 EI 1873-166X
  • 通讯作者地址:   Southwest Petr Univ
  • 被引频次:   15
  • DOI:   10.1016/j.reactfunctpolym.2019.02.001
  • 出版年:   2019

▎ 摘  要

High-efficient anti-corrosive epoxy coating, containing homogeneously dispersive graphene (Gr), has been achieved by combining non-covalent and covalent bonds. Tannic acid (TA) has been used as intercalators to disperse Gr in water via pi - pi non-covalent bond to form Gr-TA hybrids. Consequently, gamma-(2,3-epoxypropoxy) propytrimethoxysilane was used to modify the surface of Gr-TA via covalent bond to enhance the interactions between Gr-TA and epoxy. The corrosion resistance properties of the composite Gr-TA/epoxy coatings were tested by electrochemical experiment and salt spray test. The results showed that anti-corrosion properties of Gr-TA-KH560/epoxy composite coatings were hugely enhanced compared with those of the Gr-TA/epoxy and pure epoxy.