• 文献标题:   High-performance supercapacitors using graphene/polyaniline composites deposited on kitchen sponge
  • 文献类型:   Article
  • 作  者:   MOUSSA M, ELKADY MF, WANG H, MICHIMORE A, ZHOU QQ, XU J, MAJESWKI P, MA J
  • 作者关键词:   composite, graphene, supercapacitor, sponge, polyaniline
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Univ S Australia
  • 被引频次:   22
  • DOI:   10.1088/0957-4484/26/7/075702
  • 出版年:   2015

▎ 摘  要

We in this study used a commercial grade kitchen sponge as the scaffold where both graphene platelets (GnPs) and polyaniline (PANi) nanorods were deposited. The high electrical conductivity of GnPs (1460 S cm(-1)) enhances the pseudo-capacitive performance of PANi grown vertically on the GnPs basal planes; the interconnected pores of the sponge provide sufficient inner surface between the GnPs/PANi composite and the electrolyte, which thus facilitates ion diffusion during charge and discharge processes. When the composite electrode was used to build a supercapacitor with two-electrode configuration, it exhibited a specific capacitance of 965.3 F g(-1) at a scan rate of 10 mV s(-1) in 1.0 M H2SO4 solution. In addition, the composite Nyquist plot showed no semicircle at high frequency corresponding to a low equivalent series resistance of 0.35 Omega. At 100 mV s(-1), the supercapacitor demonstrated an energy density of 34.5 Wh kg(-1) and a power density of 12.4 kW kg(-1) based on the total mass of the active materials on both electrodes. To demonstrate the performance, we built an array consisting of three cells connected in series, which lit up a red light emitting diode for five minutes. This simple method holds promise for high-performance yet low-cost electrodes for supercapacitors.