• 文献标题:   Facile synthesis of poly(Safranine T)/Reduced graphene oxide nanocomposite for supercapacitors with wide potential window in aqueous neutral electrolyte
  • 文献类型:   Article
  • 作  者:   YANG YJ
  • 作者关键词:   electrochemical capacitor, poly safranine t, graphene oxide, conducting polymer, nanocomposite
  • 出版物名称:   FULLERENES NANOTUBES CARBON NANOSTRUCTURES
  • ISSN:   1536-383X EI 1536-4046
  • 通讯作者地址:   Xuchang Univ
  • 被引频次:   2
  • DOI:   10.1080/1536383X.2016.1146708
  • 出版年:   2016

▎ 摘  要

A facile method is introduced for incorporating reduced graphene oxide (rGO) into poly(safranine T) (PST) films. First, ST-functionalized GO (ST/GO) was obtained via the absorption of ST on GO in pH 7.0 phosphate buffer solution. Then rGO/PST composite was synthesized by the electropolymerization of ST and the subsequent electrochemical reduction of GO. The as-prepared PST/rGO composite films are characterized using scanning electron microscope, X-ray diffraction, and Fourier transform-infrared spectroscopy. PST/rGO composites possess a microporous structure, which creates enormous amount of pores, and therefore provides larger interfaces for charge carrier. The properties of electrochemical capacitance for PST/rGO composites have also been investigated with cyclic voltammetry (CV) and galvanostatic charge-discharge measurements. The experimental results manifest that the PST/rGO composite showed high capacitance (293.2 F g-(1)) at 20-mV s(1) CV scan and an excellent cycling stability (8.3% drop after 1000 cycles) in 0.1 M Na2SO4 electrolyte.