• 文献标题:   Ternary Fe3O4/reduced graphene oxide/phytic acid doped polyaniline hybrid based supercapacitive electrode with high capacitance retention and good cycling stability
  • 文献类型:   Article
  • 作  者:   ZHAO YX, ZHOU M, NI RF, LI Y, HUANG JY, LI ZY, CHEN JY
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1039/d3nj01150j EA APR 2023
  • 出版年:   2023

▎ 摘  要

Pseudocapacitive electrodes with high rate retention and good cycling stability are highly desirable in constructing high-performance supercapacitors due to their rapid charge/discharge capacity and long service life, but they are still a challenge to realize. Herein, a ternary Fe3O4/reduced graphene oxide/phytic acid (PA)-doped polyaniline (F-RGO-p-PANI) hybrid has been prepared to address this challenge. Prompted by the multiple synergistic effects among RGO, Fe3O4, PA, and PANI, our F-RGO-p-PANI material exhibits a high specific capacitance (C-s) of 459.1 F g(-1) with a current density of 0.5 A g(-1). Interestingly, our supercapacitor displays both high capacitance retention (similar to 83.5%) under a broad current density range (from 0.25 to 20 A g(-1)) and high cycling stability (similar to 80.8%) over 10 000 cycles under a high current density (20 A g(-1)), better than previous results. Moreover, our supercapacitor also shows a high specific energy density of 58.1 W h kg(-1) with a power density of 0.5 kW kg(-1). These results imply that our ternary F-RGO-p-PANI holds tremendous potential in fabricating rapidly charged/discharged supercapacitors.