• 文献标题:   Sulfur doped graphene quantum dots as a potential sensitive fluorescent probe for the detection of quercetin
  • 文献类型:   Article
  • 作  者:   KADIAN S, MANIK G
  • 作者关键词:   sulfur doped graphene quantum dot, fluorescent probe, quercetin, inner filter effect, quenching, pharmaceutical assay
  • 出版物名称:   FOOD CHEMISTRY
  • ISSN:   0308-8146 EI 1873-7072
  • 通讯作者地址:   Indian Inst Technol Roorkee
  • 被引频次:   4
  • DOI:   10.1016/j.foodchem.2020.126457
  • 出版年:   2020

▎ 摘  要

In this work, a novel, selective and sensitive fluorescent probe (sulfur doped graphene quantum dots, SGQDs) was designed for real-time detection of quercetin in red wine samples. SGQDs were synthesized by pyrolyzing citric acid (CA) and 3-Mercaptopropionic acid (MPA) and characterized through advanced techniques. It was observed that fluorescence intensity of SGQDs could be substantially quenched by the addition of quercetin through inner filler effect (IFE) mechanism. Additionally, a visual color change (colorless to light yellow) was also noticed after addition of quercetin into a solution of SGQDs. The change in SGQDs fluorescence intensity with varying quercetin content revealed good linearity in the 0-50.0 mu M range with regression coefficient of 0.9943 and a lowest detection limit of 0.006 mu g/mL. To authenticate the real-time application of SGQDs as a potential fluorescent probe, red wine samples having different quercetin concentrations were used for quantitative analysis, after the optimization of several analytical parameters.