• 文献标题:   High-performance capacitive behavior of layered reduced graphene oxide and polyindole nanocomposite materials
  • 文献类型:   Article
  • 作  者:   ZHOU QJ, ZHU DH, MA XM, XU JK, ZHOU WQ, ZHAO F
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Jiangxi Sci Technol Normal Univ
  • 被引频次:   24
  • DOI:   10.1039/c5ra27375g
  • 出版年:   2016

▎ 摘  要

In this work, a high-capacitance hybrid nanocomposite based on reduced graphene oxide (RGO) and polyindole (PIn) was fabricated via an in situ chemical oxidative polymerization approach. The structure and morphology of PIn/RGO were investigated by FT-IR, Raman spectroscopy, SEM and TEM. The electrochemical properties of this electrode in aqueous H2SO4 electrolyte were also investigated by cyclic voltammetry, galvanostatic charge/discharge, and electrochemical impedance spectroscopy (EIS). Compared to RGO and PIn electrodes, the PIn/RGO hybrid nanocomposite shows a large improved specific capacitance of 322.8 F g(-1) at 1.0 A g(-1), good stability with a cycling efficiency of 94.5% after 1000 cycles, and high energy density of 36 W h kg (1) at a high power density of 5000 W kg (1). The enhanced performance is proposed to arise from the synergetic effect between PIn and RGO. In addition, the symmetric PIn/RGO//PIn/RGO supercapacitor showed specific capacitance of 99.8 F g(-1) and only 3.7% decay after 1000 cycles. These results imply that PIn/RGO should be a promising electrode material for supercapacitor applications.