• 文献标题:   Graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells
  • 文献类型:   Article
  • 作  者:   GUN J, KULKARNI SA, XIU W, BATABYAL SK, SLADKEVICH S, PRIKHODCHENKO PV, GUTKIN V, LEV O
  • 作者关键词:   graphene oxide, organogel, dyesensitized solar cell, quasisolid state electrolyte
  • 出版物名称:   ELECTROCHEMISTRY COMMUNICATIONS
  • ISSN:   1388-2481 EI 1873-1902
  • 通讯作者地址:   Nanyang Technol Univ
  • 被引频次:   31
  • DOI:   10.1016/j.elecom.2012.03.025
  • 出版年:   2012

▎ 摘  要

Low concentration, as low as 0.4 wt.% graphene oxide organogels is reported for different organic solvents. The gelation of organic solvents at exceedingly low concentrations opens the door for the implementation of graphene oxides based electrolytes in various electrochemical applications. Here we demonstrate the use of acetonitrile-graphene oxide (GO) gel containing iodide/triiodide as a quasi-solid electrolyte for dye sensitized solar cells (DSCs). Electrochemical impedance studies reveal that the mass transfer barrier is not adversely affected by the presence of the minute amount of GO gel former. The achieved energy conversion efficiency (eta) for the device without GO and with 1% GO gel electrolytes is 6.9% and 7.5% respectively under one sun illumination. (C) 2012 Elsevier B.V. All rights reserved.