• 文献标题:   MnO2 Modified Reduced Graphene Oxide for Lithium-Sulfur Batteries with Improved High-Rate Cycling Stability
  • 文献类型:   Article
  • 作  者:   WU JH, LIU BY, SHEN FJ, CHEN Y, LI DY, LIU W, FAN JC, CHAO ZS
  • 作者关键词:   lithium sulfur battery, mno2, highrate cycling stability
  • 出版物名称:   SCIENCE OF ADVANCED MATERIALS
  • ISSN:   1947-2935 EI 1947-2943
  • 通讯作者地址:   Shenzhen Technol Univ
  • 被引频次:   0
  • DOI:   10.1166/sam.2019.3521
  • 出版年:   2019

▎ 摘  要

A facile and mild method was used to in situ grow MnO2 on RGO (reduced graphene oxide). This MnO2 modified RGO hybrid was designed as a host for sulfur and served as a cathode for lithium-sulfur batteries. The batteries with high loading of sulfur (similar to 70%) show high initial capacity compared with the one without MnO2, and excellent improved cycling performance at high rate of 1C, with a capacity retention of 87% after 300 cycles. The higher performance may benefit from MnO2 as a semiconductor which can facilitate electron transportation and provide migration pathways for Li+ by its tunnels structure, and as an anchor and transfer mediator to chemically trap polysulfides.