• 文献标题:   Electrochemical performance of hydrothermally synthesized N-Doped reduced graphene oxide electrodes for supercapacitor application
  • 文献类型:   Article
  • 作  者:   DAS TK, BANERJEE S, KUMAR A, DEBNATH AK, SUDARSAN V
  • 作者关键词:   reduced graphene oxide, xray photoelectron spectroscopy, supercapacitor
  • 出版物名称:   SOLID STATE SCIENCES
  • ISSN:   1293-2558 EI 1873-3085
  • 通讯作者地址:   Bhabha Atom Res Ctr
  • 被引频次:   5
  • DOI:   10.1016/j.solidstatesciences.2019.105952
  • 出版年:   2019

▎ 摘  要

In the present study, nitrogen-doped reduced graphene oxide is synthesized using hydrothermal method for high-performance supercapacitor application. The N-doping level is found to be similar to 7 at.%, and nitrogen atoms remain in pyridinic, pyrrolic and quaternary form. Because of the multiple synergistic effects of good wettability, increased electron density and a great number of active sites, the material shows a remarkably improved electrochemical behavior compared to reduced graphene oxide prepared by the same method. The electrochemical performance was measured both in the alkaline, and acidic electrolyte in two-electrode configuration. In alkaline electrolyte nitrogen doped graphene shows excellent cyclic stability (97% retention after 1000 cycles) and low internal resistance (0.207 Omega), resulting in higher specific capacitance in high current region compared to acidic electrolyte.