• 文献标题:   Graphene Oxide Modified Ag2O Nanocomposites with Enhanced Photocatalytic Activity under Visible-Light Irradiation
  • 文献类型:   Article
  • 作  者:   JI ZY, SHEN XP, YANG JL, XU YL, ZHU GX, CHEN KM
  • 作者关键词:   synthesis design, photocatalysi, nanostructure, graphene, silver oxide
  • 出版物名称:   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
  • ISSN:   1434-1948 EI 1099-0682
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   41
  • DOI:   10.1002/ejic.201301105
  • 出版年:   2013

▎ 摘  要

Owing to its unique two-dimensional structure and extraordinary physicochemical properties, graphene oxide (GO) is considered an ideal support for developing highly efficient photocatalysts. In this study, a novel Ag2O/GO nanocomposite, as a visible-light-induced photocatalyst, has been fabricated by a simple solution route. The electrostatic interactions between positively charged Ag+ and negatively charged GO sheets are responsible for the formation of the Ag2O/GO nanocomposite. The anchoring of the Ag2O nanoparticles on the GO nanosheets was confirmed by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The photocatalytic degradation of Methylene Blue (MB) under visible-light irradiation was studied to evaluate the photocatalytic activity of the Ag2O/GO nanocomposites. Due to the enhanced adsorption capacity, the smaller size of the Ag2O nanoparticles, and the improved separation of electron-hole pairs after the incorporation with GO sheets, the Ag2O/GO nanocomposites showed enhanced photocatalytic activity compared with bare Ag2O nanoparticles. In addition, the kinetics of the photocatalytic degradation reaction and a plausible photocatalytic mechanism are presented. The results pave the way to the design of highly efficient visible-light-responsive photocatalysts for the removal of organic pollutants for water purification.