• 文献标题:   Stacked Bilayer Graphene and Redox-Active Interlayer for Transparent and Flexible High-Performance Supercapacitors
  • 文献类型:   Article
  • 作  者:   JO K, LEE S, KIM SM, IN JB, LEE SM, KIM JH, LEE HJ, KIM KS
  • 作者关键词:  
  • 出版物名称:   CHEMISTRY OF MATERIALS
  • ISSN:   0897-4756 EI 1520-5002
  • 通讯作者地址:   Korea Inst Machinery Mat
  • 被引频次:   25
  • DOI:   10.1021/cm504801r
  • 出版年:   2015

▎ 摘  要

Fabrication of a transparent and flexible supercapacitor requires electrode materials that are optically transparent and mechanically flexible. Although chemical vapor deposition (CVD)-grown graphene is a promising electrode material, its use in sup ercapacitor applications is greatly limited by the low area-specific capacitance of the fabricated supercapacitor. Here, we demonstrate transparent and flexible high-performance supercapacitor using stacked bilayer graphene and an ultrathin redox-active interlayer. By inserting the redox-active layer between stacked bilayer graphene, we achieved an almost 20-fold enhancement of the area-specific capacitance (from 5.6 mu F/cm(2) to 101 mu F/cm(2)) with a thickness of electrode material for each electrode less than 2 nm. In addition, the fabricated supercapacitor exhibited excellent transparency of 75% (including the substrate's transparency) and flexibility (bending radius down to 5 mm) by virtue of the outstanding transparency and flexibility of the stacked bilayer graphene and redox-active interlayer.