• 文献标题:   Salt-assisted direct exfoliation of graphite into high-quality, large-size, few-layer graphene sheets
  • 文献类型:   Article
  • 作  者:   NIU LY, LI MJ, TAO XM, XIE Z, ZHOU XC, RAJU APA, YOUNG RJ, ZHENG ZJ
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Hong Kong Polytech Univ
  • 被引频次:   47
  • DOI:   10.1039/c3nr02173d
  • 出版年:   2013

▎ 摘  要

We report a facile and low-cost method to directly exfoliate graphite powders into large-size, high-quality, and solution-dispersible few-layer graphene sheets. In this method, aqueous mixtures of graphite and inorganic salts such as NaCl and CuCl2 are stirred, and subsequently dried by evaporation. Finally, the mixture powders are dispersed into an orthogonal organic solvent solution of the salt by low-power and short-time ultrasonication, which exfoliates graphite into few-layer graphene sheets. We find that the as-made graphene sheets contain little oxygen, and 86% of them are 1-5 layers with lateral sizes as large as 210 mu m(2). Importantly, the as-made graphene can be readily dispersed into aqueous solution in the presence of surfactant and thus is compatible with various solution-processing techniques towards graphene-based thin film devices.