• 文献标题:   Versatile preparation of graphene-based nanocomposites and their hydrogen adsorption
  • 文献类型:   Article
  • 作  者:   CHOUCAIR M, MAURON P
  • 作者关键词:   graphene, nanocomposite, storage nanomaterial, catalyst, solvothermal synthesi, spillover
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Univ Sydney
  • 被引频次:   11
  • DOI:   10.1016/j.ijhydene.2015.03.065
  • 出版年:   2015

▎ 摘  要

We report the facile and versatile preparation of graphene-based nanocornposites of magnetite, silver, titania, nickel, and silicon by solid state mechanical mixing. The composites were directly employed for nitrogen and hydrogen gas adsorption studies at 77 K and equilibrium pressure of 1 atm. Under the experimental conditions the chemically synthesised graphene support had a solid state BET surface area of 499 m(2)/g and a total reversible hydrogen uptake of 0.5 wt.%. Among our prepared nanocomposite samples, the silver nanoparticles promoted the most significant increase in hydrogen uptake per metre squared of material by 30% when compared to the parent graphene sample. However, the total hydrogen uptake by weight percentage in the studied graphenic materials remains low. The hydrogen storage capacity observed for the graphene nanocomposites can be qualitatively accounted for by considering the contributions of the catalyst particles on the hydrogen storage, the contact between catalyst and graphene, and the structural nature of the graphene surface. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.