• 文献标题:   Dopant Segregation in Polycrystalline Monolayer Graphene
  • 文献类型:   Article
  • 作  者:   ZHAO LY, HE R, ZABETKHOSOUSI A, KIM KS, SCHIROS T, ROTH M, KIM P, FLYNN GW, PINCZUK A, PASUPATHY AN
  • 作者关键词:   chemical vapor deposition, nitrogendoped graphene, dopant segregation, microraman spectroscopy, scanning tunneling microscopy
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Columbia Univ
  • 被引频次:   10
  • DOI:   10.1021/nl504875x
  • 出版年:   2015

▎ 摘  要

Heterogeneity in dopant concentration has long been important to the electronic properties in chemically doped materials. In this work, we experimentally demonstrate that during the chemical vapor deposition process, in contrast to three-dimensional polycrystals, the substitutional nitrogen atoms avoid crystal grain boundaries and edges over micron length scales while distributing uniformly in the interior of each grain. This phenomenon is universally observed independent of the details of the growth procedure such as temperature, pressure, substrate, and growth precursor.