• 文献标题:   Synthesis and characterization of a bi-functionalized lithium cobalt iron oxide/graphene nano-architectured composite material for electrochemical sensing of dopamine and as cathode in lithium-ion battery
  • 文献类型:   Article
  • 作  者:   VENKATAPRASAD G, REDDY TM, NARAYANA AL, HUSSAIN OM, GOPAL TV, SHAIKSHAVALI P
  • 作者关键词:   solgel method, solidstate sintering method, li0.3cofe2o4 particle, graphene, synergistic effect, electrochemical sensor, lithiumion batterie
  • 出版物名称:   MONATSHEFTE FUR CHEMIE
  • ISSN:   0026-9247 EI 1434-4475
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1007/s00706-021-02801-y EA JUL 2021
  • 出版年:   2021

▎ 摘  要

In this study, we have introduced a simple method for developing the lithium cobalt iron oxide (Li0.3CoFe2O4, LCFO) nanoparticles by sol-gel and solid-state sintering methods using lithium nitrate, cobalt nitrate hexahydrate, and iron oxide as precursors. The electrochemical performance of LCFO was further improved by combining graphene (LCFO-Gr). The synthesized LCFO-Gr nanocomposite exhibited cubic face-centered structure with an average particle-size distribution of 26 nm as estimated from XRD, FESEM, and TEM studies. A novel electrochemical sensor was fabricated by placing LCFO-Gr nanocomposite on the surface of glassy carbon electrode by drop-casting method, which demonstrated superior electrocatalytic activity, sensitivity, and selectivity towards the determination of dopamine. Additionally, as a cathode material, it delivered high discharge capacity of 153 mAh g(-1) with good cycling stability, suggesting LCFO-Gr nanocomposite as a prominent material for the next-generation lithium-ion batteries. [GRAPHICS]