• 文献标题:   Study on colloidal synthesis of ZnS nanospheres embedded in reduced graphene oxide materials for sodium-ion batteries and energy storage mechanism
  • 文献类型:   Article
  • 作  者:   JIN YH, SEONG H, HA MOON J, LEE SY, KIM SK, YANG MH, LEE JB, CHO SY, CHOI J
  • 作者关键词:   zinc sulfide, reduced graphene oxide, anode, insitu xrd, sodiumion batterie
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.jallcom.2023.169076 EA FEB 2023
  • 出版年:   2023

▎ 摘  要

With growing demands for large-scale energy storage, metal sulfides have received great attention due to their high theoretical capacity as anode materials for sodium-ion batteries (SIBs). However, metal sulfides have a problem of poor stability. Thus, it is important to find suitable solutions. In this work, uniform ZnS nanospheres (ZnS NSs) are synthesized through a wet chemical method. And then, by compounding with reduced graphene oxide (rGO), ZnS NSs@rGO are synthesized in which ZnS NSs are evenly distributed on rGO. When we evaluate the cycle performance, ZnS NSs@rGO deliver a high discharge capacity of 634.6 mA h g-1 at a current density of 0.5 Ag-1 after 1000 cycles. Through charge/discharge processes of in-situ XRD analysis, we confirm the sodiation/desodiation mechanism of ZnS NSs@rGO.(c) 2023 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).